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LEUCIO ROSSI


Nome: Leucio
Cognome: Rossi
Qualifica: Professore associato
Settore Scientifico Disciplinare: CHIM/07 (Fondamenti Chimici Delle Tecnologie)
Struttura di afferenza: Dipartimento di Scienze fisiche e chimiche
Email: leucio.rossiunivaq.it
Telefono Ufficio: 0862434246
Fax Ufficio: 0862434203
Home Page personale: http://ing.univaq.it/rossil


Insegnamenti tenuti - a.a.

InsegnamentoOrario di ricevimento
Chimica (I3A - Ingegneria Civile e Ambientale) Mercoledý ore 14.30 - 16.30 c/o DSFC -Coppito II (III Piano - Stanza 4.19) Si prega di contattare preventivamente il Docente
Chimica (I4A - Ingegneria Edile-Architettura U.E.) Mercoledý ore 14.30 - 16.30 c/o DSFC -Coppito II (III Piano - Stanza 4.19) Si prega di contattare preventivamente il Docente



Curriculum scientifico

(Aggiornato il 12-11-2014)

Link versione stampabile (pdf)

Nato a Roma il 29-01-1966 Professore Associato presso il Dipartimento di Chimica, Ingegneria Chimica e Materiali. Università degli Studi. Monteluco di Roio. I-67040 L’Aquila. Tel: 0862 434246; e-mail: leucio.rossi@ing.univaq.it. Carriera Accademica 21/2/1991 Laurea in Chimica con lode - Corso di Laurea in Chimica - Facoltà di Scienze Matematiche, Fisiche e Naturali dell’Università “La Sapienza” di Roma 10/1991-10/1994 Dottorato di ricerca in Scienze Chimiche (VII Ciclo) - l'Università “La Sapienza” di Roma. Tesi di dottorato: “Sintesi diastereo- ed enantioselettiva di frammenti poliossidrilati di sostanze naturali.” 3/11/1993 - 30/4/1994 Ecole Européenne des Hautes Etudes des Industries Chimiques de Strasbourg (Prof. G. Solladié). Programma di ricerca: "Sintesi asimmetrica di polioli otticamente attivi mediante l’impiego di solfossidi chirali". 26/04/1995 Ricercatore SSD C06X CHIMICA (poi reinquadrato come CHIM/07 FONDAMENTI CHIMICI DELLE TECNOLOGIE) - Facoltà di Ingegneria dell’Università degli Studi dell’Aquila Confermato nel ruolo di ricercatore universitario con decorrenza 17-07-1998. 01/11/2002 Idoneo in una procedura di valutazione comparativa a posti di professore associato, Università di Roma 3. Professore associato non confermato nel SSD CHIM/07 (D.R. n.115 del 02-12-2002). 01/11/2005 Professore Associato Confermato per il SSD CHIM/07 (D.R. n.2185 del 31-07-06). Premi 09/1997 Premio: “IS-EOS ‘97 Award for Young Chemists” 3rd International Symposium of Electroorganic Synthesis - Kurashiki (Giappone). Attività di Ricerca Elettrochimica Organica. Green Chemistry Nuove metodologie a basso impatto ambientale per la sintesi di composti di interesse industriale, farmaceutico e di sintesi. Impiego di reagenti elettrogenerati, liquidi ionici, utilizzo di CO2 come fonte di carbonio. Autore di più di 50 lavori a stampa pubblicati su riviste internazionali ad ampia diffusione e di comunicazioni a congressi internazionali e nazionali.

 

ELENCO PUBBLICAZIONI

B1)     L. Rossi.

"Product Class 6: Acyclic and Cyclic Carbamic Acid and Esters, and their Sulfur, Selenium, Tellurium, and Phosphorous Analogues" in Science of Synthesis; Houben-Weyl Method of Molecular Transformation. Vol. 18 Compounds with Four and Three Carbon-Heteroatom Bond. J.C. Knight Editor; 2005 George Thieme Verlag. Stuttgart-New York. Pp 461-648.

 

1)        C. Bonini, G. Righi, L. Rossi.

"Iterative Diastereoselective Reduction of Hydroxy Diketoesters to all 1,3,5 Syn Triols: Synthesis of C1-C10 Fragment of Nistatin A1".

Tetrahedron 1992, 48, 9801-9808.

 

2)        C. Bonini, C. Giuliano, G. Righi, L. Rossi.

"An Easy Procedure for the Higly Regioselective Conversion of Epoxides to Halohydrins".

Synthetic Communication 1992, 22(13), 1863-1870.

 

3)        C. Bonini, C. Giuliano, G. Righi, L. Rossi.

"A New Unusual C-1 Substitution of 2,3 Epoxy Alcohols with LiI: Regio and Stereoselective Obtaining of 1-Iodo 2,3 Diols and 2,3 Diols".

Tetrahedron Letters 1992, 48, 7429-7432.

 

4)        C. Bonini, R. Racioppi, L. Viggiani, G. Righi, L. Rossi.

"Enzyme-Catalyzed Desymmetrization of meso-Skipped Polyols to Useful Chiral Building Blocks".

Tetrahedron: Asymmetry 1993, 4, 793-805.

 

5)        C. Federici, G. Righi, L. Rossi, C. Bonini, L. Chiummento, M. Funicello.

"Ring Opening of 2,3-Epoxy 1-Tosylates to Halohydrins and Subsequent Elaboration to Asymmetrical Alcohols".

Tetrahedron Letters  1994, 35, 797-800.

 

6)        C. Bonini, R. Racioppi, G.Righi, L. Rossi.

"Boron Mediated One-Pot Aldol-reduction Sequence: Enantio and Diastereoselective Synthesis of Typical Polyketide Fragments".

Tetrahedron: Asymmetry  1994, 5, 173-176.

 

7)        C. Bonini, M. Checconi, G. Righi, L. Rossi.

"Enantio and Stereoselective Synthesis of (5R, 6S)-6-Acetoxyhexadecanolide, a Mosquito Oviposition Attractant Pheromone".

Tetrahedron 1995, 51, 4111-4116.

 

8)        C. Bonini, C.Federici, L. Rossi, G. Righi.

"C-1 Reactivity of 2,3-Epoxy Alcohols via Oxirane Opening with Metal Halides: Applications and Synthesis of Naturally Occurring 2,3-Octanediol, Muricatacin, 3-Octanol and 4-Dodecanolide".

J. Org. Chem. 1995, 60, 4803-4812.

 

9)        G. Solladié, C. Bauder, L. Rossi.

"Chiral Sulfoxides in Asymmetric Synthesis: Enantioselective Synthesis of the Lactonic Moiety of (+)-Compactin and (+)-Mevinolin. Application to a Compactin Analogue".

J. Org. Chem. 1995, 60, 7774-7777.

 

10)     G. Righi, L. Rossi.

"Mild Regioselective Catalytic Hydrogenation of a,b-Unsaturated Carbonyl Compounds with Lindlar Catalyst".

Synthetic Communications 1996, 26(7), 1321-1327.

 

11)     M.A. Casadei, A. Inesi, F. Micheletti Moracci, L. Rossi.

"Electrochemical Activation of Carbon Dioxide: Synthesis of Carbamates".

Chem. Commun. 1996, 2575-2576.

 

12)     M. A. Casadei, S. Cesa, M. Feroci, A. Inesi, L. Rossi, F. Micheletti Moracci.

"The O2·/CO2 System As Mild and Safe Carboxylating Reagent: Synthesis of Organic Carbonates".

Tetrahedron 1997, 53, 167-176.

 

13)     M. A. Casadei, A. Inesi, L. Rossi.

"Electrochemical Activation of Carbon Dioxide: Synthesis of Organic Carbonates".

Tetrahedron Letters 1997, 3565-3568.

 

14)     M.A. Casadei, F. Micheletti Moracci, G. Zappia, A. Inesi, L. Rossi.

"Electrogenerated Superoxide-Activated Carbon Dioxide. A New Mild and Safe Approach to Organic Carbamates".

J. Org. Chem. 1997, 62, 6754-6759.

 

15)     A. Inesi, L. Rossi, M. Feroci, M. Rizzuto.

"Electrochemically Induced Favorskii Rearrangement. a,b-Unsaturated Amides and Esters in the Electrochemical Reduction of Polyhaloketones".

New. J. Chem. 1998, 57-61.

 

16)     A. Inesi, V. Mucciante, L. Rossi.

"A Convenient Method for the Synthesis of Carbamate Esters from Amines and Tetraethylammonium Hydrogen Carbonate".

J. Org. Chem. 1998, 63, 1337-1338.

 

17)     M. Feroci, A. Inesi, L. Rossi.

"Electrochemical Activation of Carbon Dioxide. Synthesis of Organic Carbonates and Carbamates".

In Novel Trends in Electroorganic Synthesis S. Torii Ed. Springer-Verlag Tokio. 1998, 193-196.

 

18)     S. Cesa, V. Mucciante, L. Rossi.

"Tetraethylammonium Hydrogen Carbonate in Organic Synthesis: Synthesis of Oxazolidine-2,4-diones".

Tetrahedron, 1999, 55(1), 193-200.

 

19)     M. Feroci, A. Inesi, L. Rossi, G. Sleiter.

"Electrochemically Induced N-Alkylation of Pyrroles".

Eur. J. Org. Chem. 1999, 955-958.

 

20)     M. Feroci, A. Inesi, L. Rossi.

"A Simple and Convenient Method for Preparation of Sulfides".

Synthetic Communications 1999, 29(15), 2611-2615.

 

21)     M. Feroci, A. Inesi, V. Mucciante, L. Rossi.

 "New Synthesis of Oxazolidin-2-ones".

Tetrahedron Letters 1999, 40(33), 6059-6060.

 

22)     M. Feroci, A. Inesi, L. Rossi.

"The Reaction of Amines with an Electrogenerated Base. Improved Synthesis of Arylcarbamic Esters".

Tetrahedron Letters 2000, 963-966.

 

23)     M.A. Casadei, M. Feroci, A. Inesi, L. Rossi, G. Sotgiu.

"The Reaction of 1,2-Amino Alcohols with Carbon Dioxide in the Presence of 2-pyrrolidone Electrogenerated Base. New Synthesis of Chiral Oxazolidin-2-ones".

J. Org. Chem. 2000, 65, 4759-4761.

 

24)     M.A. Casadei, S. Cesa, L. Rossi.

"Electrogenerated Bases-promoted Synthesis of Organic Carbonates from Alcohols and Carbon Dioxide".

Eur. J. Org. Chem. 2000, 2445-2448.

 

25)     M. Feroci, A. Inesi, M. Orsini, L. Rossi, G. Sotgiu.

"An Efficient Electrochemical Method for the N-acryloylation of Oxazolidin-2-one Chiral Auxiliaries with a,a-di- and Trichloroketones".

J. Electroanal. Chem. 2001, 507, 89-95.

 

26)     M. Feroci, A. Inesi, L. Rossi, G. Sotgiu.

"Electrochemically Induced N-Acryloylation of Chiral Oxazolidin-2-ones"

Eur. J. Org. Chem. 2001, 2765-2769.

 

27)     M. Feroci, A. Inesi, L. Palombi, L. Rossi, G. Sotgiu.

"Electrogenerated Base-Induced N-Acylation of Chiral Oxazolidin-2-ones"

J. Org. Chem. 2001, 66, 6185-6188.

 

28)     M. Feroci, A. Inesi, L. Palombi, L. Rossi.

"Electrochemical generation of chiral oxazolidin-2-ones anions: a new procedure for the highly diastereoselective conjugate addition to nitroalkenes".

Tetrahedron: Asymmetry, 2001, 12, 2331-2335.

 

29)     L. Palombi, M. Feroci, M. Orsini, L. Rossi, A. Inesi

"Electrochemical generation of tetraethylammonium N-acetoacetyloxazolidin-2-one enolates: an easy access to a-alkylated acetoacetic derivatives".

Tetrahedron Lett. 2002, 43, 2881-2884.

 

30)     V. Mucciante, L. Rossi, M. Feroci, G. Sotgiu.

"A Safe Synthesis of Symmetrical Carbonates from Alkyl Halides and Tetraethylammonium Carbonate".

Synth. Commun. 2002, 32 (8), 1205-1210.

 

31)     A. Inesi, M. Feroci, L. Rossi, G. Sotgiu.

"Electrochemical Methods for the Synthesis and the N-Acryloylation of Oxazolidin-2-ones Chiral Auxiliaries".

Recent Res. Devel. Organic Chem. 2002, 6, 75-85.

 

32)     M. Verdecchia, M. Feroci, L. Palombi, L. Rossi.

"A Safe and Mild Synthesis of Organic Carbonates from Alkyl Halides and Tetrabutylammonium Alkyl Carbonates".

J. Org. Chem. 2002, 67, 8287-8289.

 

33)     L. Rossi.

"Tetraalkyl Ammonium Carbonates in Organic Synthesis".

Trends. Org. Chem. 2003, 10, 71-77.

 

34)     L. Rossi.

"Electrochemical Carboxylation of Alcohols. Synthesis of Organic Carbonates".

Curr. Top. Electrochem. 2004, 10, 163-169.

 

35)     L. Rossi, M. Feroci, M. Orsini, L. Palombi, A. Inesi.

"Electrolyzed CH3CN-Et4NClO4 solutions: an alternative strategy to the synthesis of b-lactams via C-N bond formation"

Analytical Mechanistic and Synthetic Organic Electrochemistry- 6th International M. Baizer Award Symposium in Honor of Dennis H. Evans and Masao Tokuda. Electrochem. Soc. Proc. 2004.

 

36)     L. Rossi, M. Feroci, A. Inesi.

"The Electrogenerated Cyanomethyl Anion in Organic Synthesis"

Mini-Reviews in Organic Chemistry 2005, 2, 343-357.

 

37)     Arcadi, A. Inesi, F. Marinelli, L. Rossi, M. Verdecchia.

"The Reaction of Acetylenic Amines with Tetraethylammonium Carbonate and Hydrogen Carbonate; Synthesis of 5-Methylene-1,3-oxazolidin-2-ones"

Synlett 2005, 67-70.

 

38)     M. Feroci, M. Orsini, L. Palombi, L. Rossi, A. Inesi.

"An electrochemical alternative strategy to the synthesis of b-lactams via N-C4 bond formation"

Electrochim. Acta, 2005, 50, 2029-2036.

 

39)     M. Feroci, M. Orsini, G. Sotgiu, L. Rossi, A. Inesi.

"Electrochemically promoted C-N bond Formation from Acetylenic Amines and CO2. Synthesis of 5-methylene-1,3-oxazolidin-2-ones."

J. Org. Chem. 2005, 70, 7795-7798.

 

40)     L. Rossi, M. Feroci, M. Verdecchia, A. Inesi.

"Electrogenerated Cyanomethyl Anion in Organic Synthesis. Synthesis of Oxazolidine-2,4-diones."

Lett. Org. Chem. 2005, 2, 731-733.

 

41)     A. Arcadi, F. Marinelli, L. Rossi, M. Verdecchia.

"A New Approach to the Synthesis of Highly Substituted 3-Pyrrolin-2-ones."

Synthesis 2006, 12, 2019-2030.

 

42)     M. Feroci, M. Orsini, L. Rossi, G. Sotgiu, A. Inesi.

"An Electrochemical Alternative Strategy to the Synthesis of b-Lactams. Part 2. C3-C4 Bond Formation."

Electrochim. Acta 2006, 51, 5540-5547.

 

43)     A. La Groia, M. Feroci, A. Inesi, L. Rossi.

"Electrochemical Synthesis of Selenocarbonates"

Lett. Org. Chem. 2006, 3, 854-856.

 

44)     M. Feroci, M. Orsini, L. Rossi, G. Sotgiu, A. Inesi.

"Electrochemically Promoted C-N Bond Formation from Amines and CO2 in Ionic Liquid BMIm-BF4: Synthesis of Carbamates"

J. Org. Chem. 2007, 72, 200-203.

 

45)     A. Arcadi, G. Bianchi, A. Inesi, F. Marinelli, L. Rossi.

"Sequential Alkylation/Heterocyclization of b-(2-Aminophenyl)-a,b-ynones Promoted by Electrogenerated Carbanions: A New Approach to Functionalized 4-Alkylquinolines"

Synlett 2007, 1031-1036.

 

46)     A. Arcadi, A. Inesi, F. Marinelli, L. Rossi, M. Verdecchia.

"An Electrochemical Alternative Approach to the Cyclization of Alkynes Bearing Proximate Malonyl Moiety"

Eur. J. Org. Chem. 2007, 2430-2437.

 

47)     L. Rossi, G. Bianchi, M. Feroci, A. Inesi.

"Electrochemically Induced Aza-Henry Reaction: A New Mild, and Clean Synthesis of a-Nitroamines"

Synlett 2007, 2505-2508.

 

48)     A. Arcadi, G. Bianchi, A. Inesi, F. Marinelli, L. Rossi.

"Electrochemical-Mediated Cyclization of 2-Alkynylanilines: A Clean and Safe Synthesis of Indole Derivatives"

Eur. J. Org. Chem. 2008, 783-787.

 

49)     G. Sotgiu, I. Chiarotto, M. Feroci, M. Orsini, L. Rossi, A. Inesi.

"An Electrochemical Alternative Strategy to the Synthesis of b-lactams Part 3 [1]. Room-temperature ionic liquids vs molecular organic solvents."

Electrochim. Acta 2008, 53(27), 7852-7858.

 

50)     M. Feroci, I. Chiarotto, L. Rossi, A. Inesi.

"Activation of Elemental Sulfur by Electrogenerated Cyanomethyl Anion: Synthesis of Substituted 2-Aminothiophenes by the Gewald Reaction."

Adv. Synth. Catal. 2008, 350(17), 2740-2746.

 

51)     G. Bianchi, M. Feroci, L. Rossi.

"Reaction of the Electrogenerated Cyanomethyl Anion with Carbonyl Compounds: A Clean and Safe Synthesis of β-Hydroxynitriles."

Eur. J. Org. Chem. 2009, 3863–3866.

 

52)     M. Feroci, M.N. Elinson, L. Rossi, A. Inesi.

"The Double Role of Ionic Liquids in Organic Electrosynthesis: Precursors of N-heterocyclic carbenes and green solvents. Henry reaction."

Electrochem. Commun. 2009, 11(7), 1523-1526.

 

53)     G. Bianchi, M. Chiarini, F. Marinelli, L. Rossi, A. Arcadi.

"Product Selectivity Control in the Heteroannulation of o-(1-Alkynyl)benzamides

Adv. Synth. Catal. 2010, 352(1), 136-142.

 

54)     M. Feroci, M. Orsini, L. Rossi, A. Inesi.

"The Double Role of Ionic Liquids in Electroorganic Synthesis: Green Solvents and Precusors of N-Heterocyclic Carbenes."

Curr. Org. Synth. 2012, 9(1), 40-52.

 

55)     A. Zhenissova A., F. Micheli, L. Rossi, S. Stendardo, P.U. Foscolo P. U, K. Gallucci.

"Experimental evaluation of Mg- and Ca- based synthetic sorbents for CO2 capture."

Chem. Eng. Res. Des. 2014, 92, 727-740.

 

56)     L. Rossi.

"Electrochemical Methodologies for the Carboxylation Reactions in Organic Synthesis. An Alternative Re-use of Carbon Dioxide."

Curr. Green Chem. in press 2014.

 

57)     L. Rossi.

"Electrochemically Induced Aza-Michael Reaction: A New, Mild, and Clean Synthesis of β-Amino Carbonyl Compounds."

Curr. Green Chem. submitted 2014.

 

58)     K. Gallucci, F. Micheli, D. Barisano, Antonio Villone, P.U. Foscolo, L. Rossi.

"CO2 Sorption Enhanced Processes by Hydrotalcite like Compounds at Different Temperature Levels".

 

Int. J. Chem React. Eng. submitted 2014.


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